A method for the synthesis of 2,3-disubstituted 2,3-dihydrobenzofurans

Author(s)
Danilo Annibali, Gerhard Ecker, Wilhelm Fleischhacker, Thomas Helml, Wolfgang Holzer, Christian Noe
Abstract

The synthesis of 2,3-disubstituted 2,3-dihydrobenzofuran diastereomers is described. The key step in the reaction sequence is the chemoselective reduction of a tert. alcohole with tert.-butylamine-borane/AICl3. The relative configuration of the substituents on the dihydrofurane moiety was assigned via NMR spectroscopy.

Organisation(s)
Journal
Monatshefte für Chemie
Volume
131
Pages
375-382
No. of pages
8
ISSN
0026-9247
DOI
https://doi.org/10.1007/s007060050318
Publication date
2000
Peer reviewed
Yes
Austrian Fields of Science 2012
3012 Pharmacy, Pharmacology, Toxicology
Portal url
https://ucrisportal.univie.ac.at/en/publications/cdb16222-f4de-42e5-80b0-911de1bda159